HYScale

HYScale technology

The HYScale technology results from intense research and development within multiple projects, such as the EU-funded projects NEWELY, Anione, and ECO2Fuel, It is based on the anion exchange membrane water electrolysis (AEMWE) technology. 

Due to its many advantages, the HYScale technology is well suited to become the future electrolyser technology delivering economical and truly green hydrogen. 

The CAPEX is estimated to be 400 € kW⁻¹ at the system level. It operates with:

  • critical raw material free catalysts,
  • fluorine-free anion exchange membranes and ionomers, 
  • a 2.9 times larger current densities than the SoA, namely at 2 A cm⁻² below 2.0 V.
 

Thanks to this solution, HYScale has a high scalability potential to active surface areas >2000 cm² allowing the European Union to maintain its leadership position in water electrolysis technologies and innovation.

Disadvantages of SoA electrolyser technologies

  1. High CAPEX (PEMWE & AWE), 
  2. Use of critical raw materials (PEMWE mainly), 
  3. Large land footprint (AWE), 
  4. Complex cell/stack design (PEMWE), 
  5. Highly corrosive electrolyte (AWE),  
  6. Need for ultra-pure water (PEMWE).
 

It’s also due to these reasons that hydrogen production cannot be achieved more cost-effectively with the PEMWE and AWE.

HYScale advantages

The use of anions exchange for water electrolysis needs to possess:

  1. High hydroxide ion conductivity,
  2. Mechanical and chemical stability,
  3. Consistent quality in terms of batch-to-batch reproducibility,
  4. Low hydrogen and oxygen crossover. 
 
Today, the biggest challenge is the limited performance and durability of the AEM and AEIs.
 
Early 2023, only two commercially available AEM and AEI are reported to have all these characteristics to withstand alkaline pHs and perform water electrolysis in a one molar potassium hydroxide (KOH) solution. Both AEMs are reported to have marginal to no degradation.

These tests were done at a current density of 1 A·cm⁻², being only a minor improvement compared to the already mature and widely used alkaline water electrolysis (AWE) with an operational capacity of 0.6 A·cm⁻². It doesn’t appear that the AIE degradation is improving neither.  Considering the consistency of the batch-to-batch quality, the AEMs failed to maintain the same performance from batch to batch.

This is due to the water-sensitive and complex chemistry and the need for all chemistries to be performed under an inert atmosphere. As a conclusion, less complex synthesis routes need to be developed.

Anion exchange membranes and ionomers

AionFLX™ from CENmat represents a significant advancement in the field of anion exchange membrane water electrolysis (AEMWE), offering a suite of highly conductive, economical, sustainable, and durable membranes and ionomers essential for water electrolysis.
 
This technology stands out for its use of sustainable PFAS free recycled polymers, marking a shift towards more environmentally friendly materials in electrolyser technology.
 
Key highlights of AionFLX™ include:
  • Flexibility: the membranes exhibit exceptional flexibility in both dry and wet states, simplifying stack assembly processes.
  • High conductivity and stability: achieved through an innovative nanophase separation technique in synthesis, forming conductive channels that allow efficient ion transport.
  • Cost-effectiveness: both the ionomer and the membrane are produced from the same batch, reducing production time and costs.
 
Notably, AionFLX™’s reliance on bio-sourced and recycled materials reduces both carbon footprint and dependency on rare materials.  In testing, AionFLX™ membranes and ionomers have demonstrated remarkable durability, withstanding high current densities in ultra-low-concentration alkaline solutions (0.1 M KOH) for over 1000 hours without degradation. 
 

Electrodes upscaling

The upscaling process of the electrodes in the HYScale project is a critical step towards achieving a final electrolysis stack with a 400 cm² surface area, designed to be both efficient and scalable for future industrial-level production.

This process is strategically divided into distinct phases, ensuring that each aspect of the technology is enhanced for optimal performance and sustainability.
Key aspects of the upscaling process include:

  • Catalyst ink upscaling: enhancing the formulation and production of catalyst ink for improved efficiency.
  • Catalyst application technique: refining the methods used to apply the catalyst, ensuring uniformity and effectiveness.
  • PTL production with reduced nickel: focusing on reducing the nickel content in the PTL to address future material scarcity concerns.
 

Stack design

At the core of the HYScale stack design is the ability to operate at a high current density of 2 A×cm⁻², which significantly lowers the capital costs (CAPEX). This is a crucial development in the electrolysis field, where efficiency and cost reduction are paramount.

The stack’s design marries the advantages of PEM and alkaline electrolysis, enabling the use of thin anion exchange membranes (AEMs) and ionomers. This allows for efficient stack sealing and better overall performance, operating effectively at the mentioned high current densities.

What makes HYScale’s stack design truly stand out is its strategic configuration, which includes:

  • Economic Porous Transport Layers (PTLs): these are carefully chosen to ensure cost-effectiveness while maintaining high performance.
  • Economic Bipolar Plates (BPP): selected for their high conductivity and good corrosion resistance, these plates are especially suited for AEM water electrolysis, which operates in low-concentration KOH solutions. This choice also mitigates issues with high-concentration alkaline solutions that typically affect the BPP durability.
  • Flow field designs: by adopting a novel design, HYScale’s stack can be scaled to large sizes without a proportional increase in costs.
Prototype of a segmented bipolar plate for future HYScale electrolysis cells, designed to monitor homogeneity.

The stack design also uses a novel approach to managing the KOH concentration, feeding the cells with very diluted solutions, which simplifies auxiliary processes and minimises the risk of corrosion. This attention to detail in the design phase underpins the project’s goal to deliver not only an efficient but also a scalable and durable solution for hydrogen production. The stack’s configuration and the choice of materials reflect a deep understanding of the challenges and requirements of modern electrolysis systems, ensuring HYScale’s position at the forefront of electrolyser innovation.

Backed up by EU-funded research

NEWELY

NEWELY is a new prototype of Anion Exchange Membrane Water Electrolysers (AEMWE) characterised by a high-performance, cost-effectiveness and durability.

The 2 kW 5-cell AEMWE stack prototype is based on hydraulic compression with novel components characterised by superior performance and stability. It is fed with pure water feedstock at a temperature of at least 45°C and it keeps this performance for 2,000 hours.

More on https://newely.eu

ANIONE

ANIONE technology will allow for scalable, efficient and low-cost production of green hydrogen from a variety of renewable energy sources. The wide-scale production of hydrogen will enable large-scale applications in grid balancing markets, in power-to-gas storage systems, and in the sustainable transport and mobility sector.

More on https://anione.eu

ECO2Fuel

ECO2Fuel aims to design, manufacture, operate, and validate the worldwide first low-temperature 1MW direct, electrochemical CO2 conversion system to produce economic and sustainable e-fuels and chemicals.

More on https://eco2fuel-project.eu/